sheet styrene will only curl up in boiling water, not really melt. If you're trying to mold it, the best thing to do is either byt a cheap vacu-forming machine (they have them really cheap in fine sclae modeler), or try the smash-molding method:
1) make a form for what you are trying to mold. (CONVEX only. nothing concave.)
2) warm the styrene slowly in the oven, until it is almost ready to melt.
3) with a pair of oven gloves, grab the styrese, bring it QUICKLY over to the form, and pull it down OVER the form.
5) let cool, the cut out the shape.
That's about the best I know. But for better modelling tips, go to:
http://www.starshipmodeler.comlook in tips and tricks to find what you need. Good luck!